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Bauer posted an update 9 months, 1 week ago
The fluorescent properties of the QD nanofluids studied were not affected after repeated electrowetting cycles.
Quantum dot nanofluids with longer alkyl chains have the most pronounced change in contact angle and were the most stable under applied voltage. The size of the nanoparticles does not significantly impact the electrowetting behavior at low concentration (3 µM), but nanofluids containing smaller diameter quantum dots show enhanced electrowetting behavior at higher concentration (27 µM). The fluorescent properties of the QD nanofluids studied were not affected after repeated electrowetting cycles.A unique reduced graphene oxide (rGO)/nitrogen doped carbon (N-C)/FeNi hybrid was successfully synthesized via a green and environmentally friendly process by means of one pot method. The morphology, phase structure, composition and electromagnetic (EM) wave absorption behavior of all hybrids were studied in detail. All rGO/N-C/FeNi hybrids are composed of rGO sheets on which there are nitrogen doped carbon and FeNi nanoparticles, and the novel structure endows the absorber with multiple scattering and reflection, interfacial polarization, dipole polarization and so on, further bringing remarkable EM wave absorption behavior. Moreover, the complex permittivity of rGO/N-C/FeNi hybrids is able to be controlled through changing the amount of GO. All results show that the rGO/N-C/FeNi-3 hybrid displays a substantial improvement in EM wave absorption performance compared with other hybrids. The minimum reflection loss (RLmin) value is -68.87 dB at 12.08 GHz with the thickness of 2.5 mm and the largest effective absorption bandwidth (EAB) achieves 6.88 GHz at 2.2 mm with RLmin value of -14.73 dB at 12.16 GHz. Our research proves that the unique structure and composition have the potential to elevate EM wave absorption performance.In the present work, we introduce a dual carbon accommodated structure in which germanium nanoparticles are encapsulated into an ordered mesoporous carbon matrix (Ge-CMK) and further coated with an amorphous carbon layer (Ge@C-CMK) through a nano-casting route followed by chemical vapor deposition (CVD) treatment. In the resultant Ge@C-CMK composite, the unique lane-like pore structure that cooperates with the amorphous carbon surface can not only mitigate the volume expansion of germanium particles, but also improve the electrical conductivity of germanium as well as facilitate Na+/K+ diffusion. When employed as the anode of sodium-ion batteries, the Ge@C-CMK electrode exhibits stable capacity as well as long-term cycling stability (a stable capacity of 176 mAh g-1 at 1 A g-1 after 5000 cycles). Furthermore, it also delivers a reversible capacity when used as the anode of potassium-ion batteries. This demonstrates that the Ge@C-CMK electrode possesses promising application potential as an alternative anode in sodium and potassium ion storage applications.In this study, we investigate the interactions between the cellulose surface and Ag nanoparticles (AgNPs) for the purpose of manufacturing hybrid nanomaterials using bacterial cellulose nanocrystals (BCNs) as a model substrate. We focus on the role of the BCN surface chemistry on the AgNP nucleation obtained by chemical reduction of Ag+ ions. Homogeneous hybrid suspensions of BCN/AgNP are produced, regardless of whether the BCNs are quasi-neutral, negatively (TBCNs) or positively charged (ABCNs). The characterization of BCN/AgNP hybrids identifies the -OH surface groups as nucleation points for AgNPs, of about 20 nm revealing that surface charges only improve the accessibility to OH groups. X-ray Absorption technics (XANES and EXAFS) revealed a high metallic Ag0 content ranging from 88% to 97%. ISO-1 price Moreover, the grafting of hydrophobic molecules on a BCN surface (HBCNs) does not prevent AgNP nucleation, illustrating the versatility of our method and the possibility to obtain bifunctional NPs. A H2O2 redox post-treatment on the hybrid induces an increase in AgNPs size, up to 90 nm as well as a shape variation (i.e., triangular). In contrast, H2O2 induces no size/shape variation for aggregated hybrids, emphasizing that the accessibility to -OH groups ensures the nucleation of bigger Ag nano-objects.In this study, we have developed a new strategy to modify the pristine polypropylene film by using cobalt-based zeolitic imidazolate framework-67. The structure and morphology of ZIF-67 were observed viapowder X-ray diffraction and scanning electron microscopy. Results indicate that the as-prepared ZIF-67 exhibits cubic structure with diameter of 80-100 nm. N2absorption-desorption test confirms the presence of mespores in the ZIF-67 cubes. The ZIF-67 was used to modify the polypropylene film that was tested in popular lithium-sulfur batteries. Electrochemical results indicate that the Li-S batteries used ZIF-67/PP films exhibit high initial specific capacity of 1365 mAh g-1 at 0.1C. Besides, it shows high capacity of 816 mAh g-1 after 300 cycles at 2C, displaying superior cycling stability. The excellent electrochemical performance is attributed the strong adsorption ability of ZIF-67/PP film between polysulfide and ZIF-67. Therefore, the proposed strategy could provide a promising approach to promoting the commercial applications of Li-S batteries.Bilingualism represents a distinctive way to investigate the interplay between brain and behaviour, and an elegant model to study the role of environmental factors in shaping this relationship. Past neuroimaging research has mainly focused on how bilingualism influences brain structure, and how eventually the brain accommodates a second language. In this paper, we discuss a more recent contribution to the field which views bilingualism as lens to understand brain-behaviour mappings from a different perspective. It has been shown, in contexts not related to bilingualism, that cognitive performance across several domains can be predicted by neuroanatomical variants determined prenatally and largely impervious to postnatal changes. Here, we discuss novel findings indicating that bilingualism modulates the predictive role of these variants on domain-specific cognition. The repercussions of these findings are potentially far-reaching on multiple levels, and highlight the need to shape more complex questions for progress in cognitive neuroscience approaches to bilingualism.