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  • Sharma posted an update 9 months ago

    This study shows that the currently used GC-MS analysis, including sample workup, is not suitable for determining the quantity of the corresponding diols derived from naphthalene and methylated naphthalenes. Alternative approaches are needed to provide a correct estimate of PAH exposure levels.Despite the increasing interest for biochar as a soil amendment, a knowledge gap remains on different particle size of biochar on soil phosphorous (P) availability and its impacts on microbial community. We hypothesized that biochar particle size and incubation temperature can significantly influence soil P availability and microbial community in subtropical acidic soil. A laboratory incubation study was established to investigate the effects of soil pH, available P and soil microbial responses to biochar addition having varying particle sizes using paddy soil and red soil under different incubation temperatures (15 °C & 25 °C). Biochar produced via pyrolysis of spent mushroom substrate feedstock was sieved into three particle sizes ((≤0.5 mm (fine), 0.5-1.0 mm (medium) and 1.0-2.0 mm (large)). The results exhibited that the fine particle biochar resulted in significantly higher release of P, soil pH, available P and bacterial species richness while simultaneously reducing the activities of phosphatase enzyme in both soils. Apprehending the impact of biochar particle size and incubation temperature, principal coordinate analysis (PCoA) predicted that soil microbial communities with fine particle biochar and high incubation temperature (25 °C) clustered separately. Redundancy analysis depicted that fine particle biochar had a direct association with available P and soil pH while high incubation temperature depicted a strong affinity for microbial communities. Hence, it is suggested that fine particle biochar and high incubation temperature may provide better habitat for microorganisms compared to the other particle sizes which may be due to improved soil pH and available P. However, a long term study of different biochar particles application in subtropical acidic soil needs to be pursued further for a more comprehensive understanding on this issue.Shiga-toxigenic Escherichia coli (STEC) are important human pathogens associated with diarrhea and in some cases haemorrhagic colitis. Contaminated food derived from cattle and wildlife species are often associated with disease outbreaks. In this study, we report the prevalence, serogroup diversity and virulence profiles of STEC strains derived from cattle, rusa deer and pig. Of the 422 samples analyzed, STEC were detected in 40% (80/200) of cattle, 27.0% (33/122) of deer and 13.0% (13/100) of pigs. STEC isolates belonged to 38 O-serogroups whereby 5.2% (24/462) of the isolates belonged to clinically important EHEC-7 serogroups O26 (n = 2), O103 (n = 1), O145 (n = 3) and O157 (n = 18). Fourteen serogroups (O26, O51, O84, O91, O100, O104, O110, O117, O145, O146, O156, O157, O177 and ONT) displayed multiple virulence profiles. We also identified two serovars (O117 and O119) in deer which are not well-documented in epidemiological surveys. 73.7% (28/38) of recovered O-serogroups are known to be associated with satabases. Upadacitinib None of the ST’s recovered in deer were observed in domestic species. Our findings shows that food associated animals found on the tropical island of Mauritius carry a diversity of STEC strains with many serovars known to be associated with human disease. This report indicates that increased awareness, surveillance and hygienic attention at critical stages of the human food chain are warranted.Unexpected social or economic events have been shown to negatively impact mental health and wellbeing. The result of the 2016 Brexit referendum in the UK has been associated with an increase in uncertainty and consequent anxiety. This study analyses antidepressant prescription trends in the 533 constituencies of England in the year before and three years following the referendum. We examine associations between prescription trends and constituency-level voting patterns in the referendum and later support for the March 2019 “Revoke Article 50”, signed by more than 6 million UK citizens. A mixed model analysis revealed the rate of increase in antidepressant prescription trends to be steeper in Leave constituencies and in areas that did not support the petition, after controlling for constituency education, socioeconomic status, median age, total population, and seasonal effects. Proposed interpretations are provided, along with recommendations for future research. Implications for this study include redoubling mental health care service in areas that show significantly higher mental distress following a major political event.One-pot conversion of alginic acid, which was derived from brown algae, to furfural was investigated using various solid acid catalysts. Among the solid acid catalysts tested, Amberlyst-15 showed the highest activity in furfural production in aqueous media. When the effect of reaction media was examined by applying various organic solvent mixtures, it was found that γ-butyrolactone/water co-solvent system was selected as the most appropriate system for the reaction. Maximum furfural yield of 32.2% was obtained using Amberlyst-15 in the γ-butyrolactone/H2O at 210 °C for 20 min. Catalyst showed gradual deactivation behavior as the reaction proceeded, although the catalyst recovered its activity upon the simple treatment with sulfuric acid. N2 adsorption-desorption experiments, Fourier-transform infrared spectroscopy (FT-IR), back titration, and CHNS analysis were applied to investigate the physicochemical property of post-reaction samples, confirming that the leaching of the active sulfonic acid group and decrease in acid density was the major cause of deactivation.Xinqing Wetland and Shengjin Lake Wetland are the main habitats of Hooded Crane in China. However, in recent years, the irrational land use situation of occupied wetlands has occurred frequently, resulting in the destruction of the breeding of the Hooded Crane population and the destruction of the wintering habitat. The paper takes Xinqing Wetland and Shengjin Lake Wetland as the research area, and uses landscape ecology and geostatistics as the theoretical basis to reveal the changes of land landscape in the study area, and analyze the main breeding and wintering habitat types of Hooded Crane. The landscape ecological risk assessment model is constructed by the landscape pattern index method, and the ecological risk in the study area is divided into five levels extremely low ecological risk, low ecological risk, medium ecological risk, high ecological risk and extremely high ecological risk. The landscape ecological risk of the study area is analyzed from the aspects of single landscape type, spatial distribution characteristics and time series changes.

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