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Castaneda posted an update 5 months ago
A key way to prevent undesirable fouling of any structure in the marine environment, without harming any microorganisms, is to use a polymer film with high hydrophobicity. The polymer film, which was simply prepared from a blend of hydrophobic polydimethylsiloxane elastomer and hydrophilic polyurethane, showed improved properties and economic viability for antifouling film for the marine industry. The field emission scanning electron microscope and energy dispersive X-ray spectrometer (FESEM and EDX) results from the polymer blend suggested a homogenous morphology and good distribution of the polyurethane disperse phase. The PDMSPU blend (955) film gave a water contact angle of 103.4° ± 3.8° and the PDMS film gave a water contact angle of 109.5° ± 4.2°. Moreover, the PDMSPU blend (955) film could also be modified with surface patterning by using soft lithography process to further increase the hydrophobicity. It was found that PDMSPU blend (955) film with micro patterning from soft lithography process increased the contact angle to 128.8° ± 1.6°. Rimegepant The results from a field test in the Gulf of Thailand illustrated that the bonding strength between the barnacles and the PDMSPU blend (955) film (0.07 MPa) were lower than the bonding strength between the barnacles and the carbon steel (1.16 MPa). The barnacles on the PDMSPU blend (955) film were more easily removed from the surface. This indicated that the PDMSPU blend (955) exhibited excellent antifouling properties and the results indicated that the PDMSPU blend (955) film with micro patterning surface could be employed for antifouling application.This article presents a comprehensive thermomechanical analysis and failure assessment in the drilling of glass fiber-reinforced polymer (GFRP) composites with different thicknesses using a CNC machine and cemented carbide drill with a diameter of 6 mm and point angles of ϕ = 118°. The temperature distribution through drilling was measured using two techniques. The first technique was based on contactless measurements using an IR Fluke camera. The second was based on contact measurements using two thermocouples inserted inside the drill bit. A Kistler dynamometer was used to measure the cutting forces. The delamination factors at the hole exit and hole entry were quantified by using the image processing technique. Multi-variable regression analysis and surface plots were performed to illustrate the significant coefficients and contribution of the machining variables (i.e., feed, speed, and laminate thickness) on machinability parameters (i.e., the thrust force, torque, temperatures, and delamination). It is concluded that the cutting time, as a function of machining variables, has significant control over the induced temperature and, thus, the force, torque, and delamination factor in drilling GFRP composites. The maximum temperature recorded by the IR camera is lower than that of the instrumented drill because the IR camera cannot directly measure the tool-work interaction zone during the drilling process. At the same cutting condition, it is observed that by increasing the thickness of the specimen, the temperature increased. Increasing the thickness from 2.6 to 7.7 had a significant effect on the heat distribution of the HAZ. At a smaller thickness, increasing the cutting speed from 400 to 1600 rpm decreased the maximum thrust force by 15%. The push-out delaminations of the GFRP laminate were accompanied by edge chipping, spalling, and uncut fibers, which were higher than those of the peel-up delaminations.Dipsacus asper wall (DA) is an ancient Chinese medicinal material that has long been used to maintain the health of human bones. The present study aimed to evaluate the osteogenic differentiation of periodontal ligament stem cells (PDLSCs) of Dipsacus asper wall extracts (DAE). Microwave-assisted alcohol extraction of 100 mesh DA powder under optimal conditions can obtain 58.66% (w/w) yield of the crude extract. PDLSCs have excellent differentiation potential. PDLSCs treated with DA extract (DAE) underwent osteogenesis, exhibiting a higher expression of the Col-1, ALP, Runx2, and OCN genes, and had a 1.4-fold increase in mineralization, demonstrating the potential of DAE to promote osteogenic differentiation. After the addition of PI3K inhibitor LY294002, the expression of osteogenic genes was significantly inhibited, confirming that PI3K is an important pathway for DAE to induce osteogenesis. Mix DAE with polycaprolactone/polyethylene glycol (PCL/PEO) to obtain nanofibers with a diameter of 488 nm under optimal electrospinning conditions. The physical property analysis of nanofibers with and without DAE includes FTIR, mechanical strength, biodegradability, swelling ratio and porosity, and cell compatibility. When cells induced by nanofibers with or without DAE, the mineralization of PDLSCs cultured on PCL/PEO/DAE was 2.6-fold higher than that of PCL/PEO. The results of the study confirm that both DAE and PCL/PEO nanofibers have the effect of promoting osteogenic differentiation. In order to obtain the best induction effect, the optimal amount of DAE can be discussed in future research.Atomistic modeling methods are successfully applied to understand interfacial interaction in nanoscale size and analyze adhesion mechanism in the organic-inorganic interface. In this paper, we review recent representative atomistic simulation works, focusing on the interfacial bonding, adhesion strength, and failure behavior between polymer film and silicate glass. The simulation works are described under two categories, namely non-bonded and bonded interaction. In the works for non-bonded interaction, three main interactions, namely van der Waals interaction, polar interaction, and hydrogen bonds, are investigated, and the contributions to interfacial adhesion energy are analyzed. It is revealed that the most dominant interaction for adhesion is hydrogen bonding, but flexibility of the polymer film and modes of adhesion measurement test do affect adhesion and failure behavior. In the case of bonded interactions, the mechanism of covalent silane bond formation through condensation and hydrolysis process is reviewed, and surface reactivity, molecular density, and adhesion properties are calculated with an example of silane functionalized polymer.